Determination of Test Methods to Quantify the Effects of Organic and Inorganic Constituents in Silica Sand Used for Construction

Determination of Test Methods to Quantify the Effects of Organic and Inorganic Constituents in Silica Sand Used for Construction

Florida-produced fine aggregates are generally of suitable quality, and deleterious effects associated with organic matter are uncommon. However, naturally occurring organic constituents can affect cement hydration and early-age strength development depending on their concentration, composition, and interaction with cementitious phases. The sands evaluated in this study contained relatively low organic contents, making establishment of a universal organic-content threshold impractical. FDOT currently uses AASHTO T 21 as the primary screening method for potentially deleterious organic impurities and requires AASHTO T 71 testing when screening results indicate concern. This framework should be maintained. AASHTO T 21 provides effective statewide screening, while AASHTO T 71 provides performance-based confirmation. However, AASHTO T 21 is qualitative, and AASHTO T 71 requires extended testing that can delay aggregate acceptance decisions. Neither elemental analysis nor the Modified Walkley-Black method demonstrated sufficient precision, consistency, or correlation with AASHTO T 21 to support statewide acceptance criteria. However, MWB may be used to establish minespecific organic-carbon baselines, and isothermal calorimetry may be used to establish mine-specific hydration-response baselines. Deviations from these baselines may indicate the need for additional evaluation, including AASHTO T 71 testing. Organic-carbon contents below approximately 0.015% did not measurably affect hydration or compressive strength. Alkaline washing reduced measured organic content and increased pH but did not consistently improve strength. The ASTM C109 hand-tamped consolidation procedure is recommended for AASHTO T 71 mortar cube fabrication. Trace inorganic constituents, including phosphorus, did not produce measurable strength effects.


Infrastructure Assets: Highway Assets
Resource Types: Research Report
Capabilities: Tools & Technology
Management Processes: Performance Based Planning & Programming

Publisher:
Florida Department of Transportation

Publication Year:
2026

External Link

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